Cleaning, Etching, Activation, and Deposition
Cleaning is a mandatory step in every processes of surface
modifications. Basic cleaning operations are usually performed with
a chemical treatment outside a vacuum chamber. But the treated
sample inevitably pollute, being transported. Therefore the final
cleaning has to be accomplished in the vacuum chamber. Plasma
etching is an effective method of cleaning in vacuum. The main
advantage of this method is the ability to process any kind of
materials. Plasma etching is being used worldwide to remove organic and
inorganic contamination, increase wettability, increase bond
strength, and remove residues. These processes are under precisely controlled conditions, without the safety hazards and liquid wastes
associated with wet cleaning and etching. Besides, plasma surface treatment processing usually activate the surface, promoting much better adhesion of deposited
film.
The process of magnetron deposition can be improved
considerably, the dedicated plasma source operating at matched
regime being used. The anode layer accelerator (ALA) is one of prospective sources for this
purpose. It can be used for plasma assisted magnetron sputtering,
e.g. it is possible to use ALA to keep the magnetron target highly
pure or keep constant conditions of synthesis on a sample.
The ALA based devices can be effectively used to produce
composite and multilayer thin films. The lower rate of the film
growth (compared to the case of magnetron deposition) enable more
precise control of its thickness. This can be important for optical
and multilayer coatings.
For nano-scale surface modification the oblique etching at the
regimes with low currents under low pressure can be used. Depending
on the used regime of the substrate treatment, various liquid crystal alignments
can be obtained. The wide range of alignments
types can be obtained using various combinations of processing
regimes and liquid crystal types, even the same materials being
used. This method is contact-free, it is easy to use templates to
create cells with multidomain liquid crystal alignment.
The use of the ALA based devices offers a wide variety of
advantages and can be effectively used in vacuum technologies to
obtain single- and multi-layer coatings with various thicknesses
and purposes as these devices are rater easily scalable. The
creation of surface anisotropy is one more application of the ALA
based devices, e.g. for liquid crystal alignment.
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