Nanoscale physics 

Some microscopical insight on the moving-line phenomenon for non-stable-interface Auger spectra 
Mishchuk O.A. 
Tribology and Surface Chemistry Laboratory of S&R Institute “MASMA”, 
Ministry for Energy and Coal Industry of Ukraine 
46 Academician Palladin Avenue, 03142 Kyiv, Ukraine. 
E-mail: mishchuk@masma.ua 

The natural non-stable nanointerfaces in overbased sulfonate micelles are easy to generate under electron-probe acting the moving spectral lines (ML) [1] (Figure). The initial appearance of a very thin abnormal spectral line ML1 was attributed to the effects of Coster-Kronig transitions for sulfur (VI) cation S+L1L23V (for electronegative elements the ML is observed for the first time experimentally and with new peculiarities). This ML1 displaced and increased continuously to higher energy position of a normal Auger line S L23VV, after which we can see visible increases of the Ca and S concentrations (structural changes in micelles), reverse displacement of ML1 and appearance and next displacement of a new line ML2. 
For electron-probe-induced nanostructural relaxation, the presented results cause the hypothesis of a non-quasi-atomic coherent behavior of the Coster-Kronig processes from L1 subshell with participation of resonating S-O (Ca-O) hybridized valence levels (through exciton creation) at the charged nanointerfaces. 
Fig. Moving line room temperature phenomena (ML1 and ML2) for the electron-induced Auger spectra of calcium sulfonate carbonate nanomicelles: selectively on (1) 59 min; (2) 170 min; (3) 287 min after the first observation of ML1. (See 2nd abstract here) 

1.	Mishchuk O.A. Resonant electron emission within moveable energy-range from changeable interfaces: Soliton-like nanoreality / In: NANO-2017, Abs. Int. conf., Chernivtsi, Ukraine, Aug. 23-26, 2017. - Kyiv: SME Burlaka, 2017. - P. 501. - http://www.iop.kiev.ua/~nano2017/files/Abstract_book.pdf